Filtration Articles & Insights | PoreFiltration

Process Cartridge Filters for Aggressive Chemical Filtration

Written by David Keay | Nov 13, 2025
Aggressive chemical processes place exceptional demands on filtration systems. Whether filtering strong acids, alkalis, oxidising agents, or organic solvents, the filter cartridges and housings must resist chemical attack, maintain mechanical integrity, and ensure product purity

Selecting the correct cartridge filter and housing combination is therefore critical to achieving safe, reliable, and long-term performance.

This article explains how process cartridge filters are applied in aggressive chemical service, identifies suitable filter media and housing materials, and introduces the use of tantalised housings for the most extreme corrosive environments.

Understanding Aggressive Chemical Filtration

Aggressive chemicals include strong acids, alkalis, and solvents that attack most common materials. Examples include:

  • Acids: Sulfuric (H₂SO₄), Hydrochloric (HCl), Nitric (HNO₃), Hydrofluoric (HF)
  • Alkalis: Sodium hydroxide (NaOH), Potassium hydroxide (KOH)
  • Oxidising agents: Hydrogen peroxide (H₂O₂), Sodium hypochlorite (NaOCl)
  • Organic solvents: Acetone, MEK, toluene, DMF

Each of these can rapidly corrode or embrittle polymer or metal housings and degrade filter media if materials are not correctly matched.

Cartridge Filter Options for Aggressive Chemicals

The choice of cartridge depends on the chemical composition, operating temperature, and required purity level.

Filter Type

Construction

Chemical Resistance

Typical Applications

All-Polypropylene (PP) Depth & Pleated Filters

Melt-blown or pleated PP media with PP hardware

Excellent for most acids, alkalis, and aqueous salts

General chemical blending, acid/alkali filtration, cleaning baths

PVDF Pleated Filters

PVDF membrane or depth media with PVDF hardware

Excellent resistance to oxidisers and many solvents

Oxidising agents, solvent-based blends

PTFE Membrane Filter

Hydrophobic or hydrophilic PTFE membrane with PFA or PP support

Outstanding resistance to virtually all chemicals

Concentrated acids, organic solvents, semiconductor-grade fluids

Sintered St.St.

Rigid porous structure

Chemically inert and mechanically strong

High-solids acids or abrasive chemical processes

 

Filter Housing Materials for Aggressive Chemical Filtration

Filter housings are often the limiting component in chemical filtration systems. Material choice must consider chemical compatibility, temperature, pressure, and mechanical robustness.

Housing Material

Typical Use

Advantages

Limitations

Polypropylene (PP)

Acids, alkalis, aqueous solutions

Low cost, non-metallic, lightweight

Limited to ~80°C; not suited for strong oxidisers or solvents

PVDF (Polyvinylidene Fluoride)

Oxidising agents, strong acids

Excellent oxidiser resistance; clean construction

Moderate pressure limits (~6 bar)

PFA / PTFE

High-purity and semiconductor chemicals

Universal compatibility, inert, ultra-clean

Expensive; limited pressure rating

Glass-Reinforced Polypropylene (GRPP)

Utility and plant service

Improved mechanical strength

Still not compatible with strong oxidisers

PTFE-Lined Stainless Steel

Concentrated acids, solvents

Combines metal strength with PTFE inertness

Lining integrity critical; avoid mechanical damage

Tantalum-Lined (Tantalised) Stainless Steel

Highly corrosive acids including HF, hot HNO₃, mixed oxidisers

Exceptional corrosion resistance rivaling glass or PFA; withstands high pressure and temperature

High cost; longer lead time

Solid Alloy (Hastelloy, Alloy 20, Inconel)

Mixed acid duties and hot oxidisers

High mechanical and thermal strength

Costly and still limited in halide-rich acids (HF, HCl)

 

Tantalised (Tantalum-Lined) Housings Explained

Tantalising is the process of applying a thin layer (typically 50–100 µm) of tantalum metal to the internal surfaces of a stainless steel housing. This can be achieved through thermal spray, chemical vapour deposition, or explosive bonding.

Tantalum forms a passive oxide film (Ta₂O₅) that is highly resistant to almost all acids — including hydrofluoric acid (HF), which attacks glass, and hot nitric acid (HNO₃), which attacks most metals.

Advantages

  • Compatible with virtually all mineral acids, including HF, aqua regia, and mixed oxidisers.
  • Maintains mechanical strength of stainless steel with chemical inertness of glass or PTFE.
  • Operates at temperatures >200°C and pressures >10 bar.
  • Non-contaminating — ideal for fine chemicals, catalysts, and pharmaceutical intermediates.

Limitations

  • High capital cost and specialised fabrication.
  • Lead times typically longer than standard housings.
  • Must avoid physical damage to coating during installation or cartridge change-out.

Typical use cases:

  • Mixed acid systems in fine chemical production.
  • Hydrofluoric acid filtration in fluoropolymer or catalyst manufacture.
  • Concentrated nitric acid recirculation lines.
  • High-temperature oxidising or halogenated solvent service.

Matching Cartridge and Housing to Application

Application

Typical Chemicals

Recommended Cartridge

Recommended Housing

Notes

Acid Pickling / Metal Finishing

HCl, H₂SO₄, HNO₃

All-PP depth & pleated depth (5–20 µm)

Glass-reinforced PP or PTFE-lined SS

Economical for moderate acids

Caustic Cleaning Baths

NaOH, KOH

All-PP depth depth & pleated depth (1–10 µm)

Polypropylene or GRPP

Compatible, cost-effective

Oxidising Agents

NaOCl, H₂O₂

PVDF pleated (0.5–5 µm)

PVDF housing

Avoid PP; PVDF maintains stability

Organic Solvent Filtration

MEK, toluene, acetone

PTFE membrane (0.2–1 µm hydrophobic)

PTFE or PFA housing

Ensure Kalrez® or FEP seals

High-Purity Acid Supply (Semiconductor)

HF, HCl, H₂SO₄

Hydrophilic PTFE membrane (0.1–0.5 µm)

All-PFA housing

Zero metallic contamination

Pharmaceutical API Synthesis

Mixed solvents and reagents

PVDF or PTFE membrane (0.2–1 µm)

PTFE-lined or tantalised SS housing

Use where oxidisers and solvents are mixed

Fine Chemical Production (Mixed Acids)

HF + HNO₃ + H₂SO₄

PTFE membrane (0.2 µm)

Tantalised SS housing

Handles extreme acid blend; long service life

Etching / CMP Slurries

H₂O₂, NH₄OH, abrasives

PVDF or PTFE hybrid

PFA or PVDF housing

Ensures ultra-clean, particle-free output

 

System Design and Safety Considerations

  1. Seal Materials:

    • FEP-encapsulated Viton®, Kalrez®, or PTFE are preferred.
    • Avoid Buna-N or EPDM in oxidising or solvent environments.

  2. Mechanical Integrity:

    • Pressure ratings must exceed operating conditions.
    • For mixed acid systems, use tantalised housings or thick-wall PTFE-lined steel.

  3. Avoid Adhesives:

    • Specify thermally welded or fused cartridge construction to eliminate extractables.

  4. Grounding and Safety:

    • Essential for solvent and flammable chemical systems.

  5. Inspection and Maintenance:

    • Regularly inspect housings — especially lined or tantalised types — for coating damage.
    • Replace filters based on differential pressure rather than time to maintain safety margins.

 

In aggressive chemical service, chemical compatibility is just as critical as filtration efficiency.

  • Polypropylene and PVDF systems are suitable for most acids, alkalis, and oxidisers.
  • PTFE and PFA systems deliver the ultimate in chemical inertness and purity.
  • And for the most extreme acid mixtures — especially those containing hydrofluoric acid or mixed oxidising acidstantalum-lined housings provide the only practical long-term solution, combining the strength of stainless steel with the corrosion resistance of glass or PTFE.

By carefully pairing the correct cartridge media and housing construction, engineers can achieve safe, efficient, and durable filtration performance even under the harshest chemical conditions.

You can read more about filtration solutions for Chemicals & Solvents here and if you have any questions then you can give us a call or send us an email - we’d be more than happy to help. 

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