Process Cartridge Filters for Aggressive Chemical Filtration
Selecting the correct cartridge filter and housing combination is therefore critical to achieving safe, reliable, and long-term performance.
This article explains how process cartridge filters are applied in aggressive chemical service, identifies suitable filter media and housing materials, and introduces the use of tantalised housings for the most extreme corrosive environments.
Understanding Aggressive Chemical Filtration
Aggressive chemicals include strong acids, alkalis, and solvents that attack most common materials. Examples include:
- Acids: Sulfuric (H₂SO₄), Hydrochloric (HCl), Nitric (HNO₃), Hydrofluoric (HF)
- Alkalis: Sodium hydroxide (NaOH), Potassium hydroxide (KOH)
- Oxidising agents: Hydrogen peroxide (H₂O₂), Sodium hypochlorite (NaOCl)
- Organic solvents: Acetone, MEK, toluene, DMF
Each of these can rapidly corrode or embrittle polymer or metal housings and degrade filter media if materials are not correctly matched.
Cartridge Filter Options for Aggressive Chemicals
The choice of cartridge depends on the chemical composition, operating temperature, and required purity level.
|
Filter Type |
Construction |
Chemical Resistance |
Typical Applications |
|
All-Polypropylene (PP) Depth & Pleated Filters |
Melt-blown or pleated PP media with PP hardware |
Excellent for most acids, alkalis, and aqueous salts |
General chemical blending, acid/alkali filtration, cleaning baths |
|
PVDF membrane or depth media with PVDF hardware |
Excellent resistance to oxidisers and many solvents |
Oxidising agents, solvent-based blends |
|
|
Hydrophobic or hydrophilic PTFE membrane with PFA or PP support |
Outstanding resistance to virtually all chemicals |
Concentrated acids, organic solvents, semiconductor-grade fluids |
|
|
Rigid porous structure |
Chemically inert and mechanically strong |
High-solids acids or abrasive chemical processes |
Filter Housing Materials for Aggressive Chemical Filtration
Filter housings are often the limiting component in chemical filtration systems. Material choice must consider chemical compatibility, temperature, pressure, and mechanical robustness.
|
Housing Material |
Typical Use |
Advantages |
Limitations |
|
Polypropylene (PP) |
Acids, alkalis, aqueous solutions |
Low cost, non-metallic, lightweight |
Limited to ~80°C; not suited for strong oxidisers or solvents |
|
PVDF (Polyvinylidene Fluoride) |
Oxidising agents, strong acids |
Excellent oxidiser resistance; clean construction |
Moderate pressure limits (~6 bar) |
|
PFA / PTFE |
High-purity and semiconductor chemicals |
Universal compatibility, inert, ultra-clean |
Expensive; limited pressure rating |
|
Glass-Reinforced Polypropylene (GRPP) |
Utility and plant service |
Improved mechanical strength |
Still not compatible with strong oxidisers |
|
PTFE-Lined Stainless Steel |
Concentrated acids, solvents |
Combines metal strength with PTFE inertness |
Lining integrity critical; avoid mechanical damage |
|
Tantalum-Lined (Tantalised) Stainless Steel |
Highly corrosive acids including HF, hot HNO₃, mixed oxidisers |
Exceptional corrosion resistance rivaling glass or PFA; withstands high pressure and temperature |
High cost; longer lead time |
|
Solid Alloy (Hastelloy, Alloy 20, Inconel) |
Mixed acid duties and hot oxidisers |
High mechanical and thermal strength |
Costly and still limited in halide-rich acids (HF, HCl) |
Tantalised (Tantalum-Lined) Housings Explained
Tantalising is the process of applying a thin layer (typically 50–100 µm) of tantalum metal to the internal surfaces of a stainless steel housing. This can be achieved through thermal spray, chemical vapour deposition, or explosive bonding.
Tantalum forms a passive oxide film (Ta₂O₅) that is highly resistant to almost all acids — including hydrofluoric acid (HF), which attacks glass, and hot nitric acid (HNO₃), which attacks most metals.
Advantages
- Compatible with virtually all mineral acids, including HF, aqua regia, and mixed oxidisers.
- Maintains mechanical strength of stainless steel with chemical inertness of glass or PTFE.
- Operates at temperatures >200°C and pressures >10 bar.
- Non-contaminating — ideal for fine chemicals, catalysts, and pharmaceutical intermediates.
Limitations
- High capital cost and specialised fabrication.
- Lead times typically longer than standard housings.
- Must avoid physical damage to coating during installation or cartridge change-out.
Typical use cases:
- Mixed acid systems in fine chemical production.
- Hydrofluoric acid filtration in fluoropolymer or catalyst manufacture.
- Concentrated nitric acid recirculation lines.
- High-temperature oxidising or halogenated solvent service.
Matching Cartridge and Housing to Application
|
Application |
Typical Chemicals |
Recommended Cartridge |
Recommended Housing |
Notes |
|
Acid Pickling / Metal Finishing |
HCl, H₂SO₄, HNO₃ |
All-PP depth & pleated depth (5–20 µm) |
Glass-reinforced PP or PTFE-lined SS |
Economical for moderate acids |
|
Caustic Cleaning Baths |
NaOH, KOH |
All-PP depth depth & pleated depth (1–10 µm) |
Polypropylene or GRPP |
Compatible, cost-effective |
|
Oxidising Agents |
NaOCl, H₂O₂ |
PVDF pleated (0.5–5 µm) |
PVDF housing |
Avoid PP; PVDF maintains stability |
|
Organic Solvent Filtration |
MEK, toluene, acetone |
PTFE membrane (0.2–1 µm hydrophobic) |
PTFE or PFA housing |
Ensure Kalrez® or FEP seals |
|
High-Purity Acid Supply (Semiconductor) |
HF, HCl, H₂SO₄ |
Hydrophilic PTFE membrane (0.1–0.5 µm) |
All-PFA housing |
Zero metallic contamination |
|
Pharmaceutical API Synthesis |
Mixed solvents and reagents |
PVDF or PTFE membrane (0.2–1 µm) |
PTFE-lined or tantalised SS housing |
Use where oxidisers and solvents are mixed |
|
Fine Chemical Production (Mixed Acids) |
HF + HNO₃ + H₂SO₄ |
PTFE membrane (0.2 µm) |
Tantalised SS housing |
Handles extreme acid blend; long service life |
|
Etching / CMP Slurries |
H₂O₂, NH₄OH, abrasives |
PVDF or PTFE hybrid |
PFA or PVDF housing |
Ensures ultra-clean, particle-free output |
System Design and Safety Considerations
-
Seal Materials:
- FEP-encapsulated Viton®, Kalrez®, or PTFE are preferred.
- Avoid Buna-N or EPDM in oxidising or solvent environments.
-
Mechanical Integrity:
- Pressure ratings must exceed operating conditions.
- For mixed acid systems, use tantalised housings or thick-wall PTFE-lined steel.
-
Avoid Adhesives:
- Specify thermally welded or fused cartridge construction to eliminate extractables.
-
Grounding and Safety:
- Essential for solvent and flammable chemical systems.
-
Inspection and Maintenance:
- Regularly inspect housings — especially lined or tantalised types — for coating damage.
- Replace filters based on differential pressure rather than time to maintain safety margins.
In aggressive chemical service, chemical compatibility is just as critical as filtration efficiency.
- Polypropylene and PVDF systems are suitable for most acids, alkalis, and oxidisers.
- PTFE and PFA systems deliver the ultimate in chemical inertness and purity.
- And for the most extreme acid mixtures — especially those containing hydrofluoric acid or mixed oxidising acids — tantalum-lined housings provide the only practical long-term solution, combining the strength of stainless steel with the corrosion resistance of glass or PTFE.
By carefully pairing the correct cartridge media and housing construction, engineers can achieve safe, efficient, and durable filtration performance even under the harshest chemical conditions.
You can read more about filtration solutions for Chemicals & Solvents here and if you have any questions then you can give us a call or send us an email - we’d be more than happy to help.
You can also read more in our blogs:
- Prefiltration: Choosing The Right Cartridge Filters
- Navigating Different Housings for Cartridge Filter Applications
- Guide to Selecting the Right Micron Rating
PoreFiltration – Making your filtration systems work harder




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